Metal base work, acid treating

The corrosion inhibitor of the present invention comprises a mixture containing (a) the reaction product of a nitrogen containing compound containing at least one active hydrogen attached to the nitrogen atom per molecule; a ketone having at least one hydrogen atom attached to the carbon atom alpha to...     

The invention is for a process and composition for pickling metals, especially iron based metals, prior to metal finishing. A hydrohalide acid pickling solution is used which solution is characterized by the addition of urea. The urea substantially reduces, even completely eliminates, the excessive liberation...     

A stripping solution comprising between 80 and 98% H.sub.2 SO.sub.4, between 0.5 and 4% HClO.sub.4, between 0.5 and 4% CrO.sub.3 and H.sub.2 O. The principal application of the solution is to remove polymerized photoresist layers formed during the manufacture of semiconductor devices.

A synergistic mixture of an alkynyl cycloalkanol and an N,N'-dicycloalkyl-thiourea is used as an inhibitor in protecting metals from acid attack when cleaning said metals with an acid solution.

A two-constituent combination of phosphoric and nitric acids with a minimal volume of water. The composition is designed to remove stains, corrosion, dirt and encrustations from coinage metals composed mainly of copper, silver, brass, bronze and gold. No abrading action is required and there are no adverse...     

A method of pickling metallic material particularly for the continuous treatment of material in strip or wire form and especially such material consisting of stainless steel, wherein the material after annealing is subjected in a first step to the chemical attack of a first aqueous solution which is...     

An acidic cleaning composition comprising at least 0.1 weight percent of at least one member selected from the group consisting of furan-carboxylic acid and derivatives thereof having the following formula I and tetrahydrofuran-carboxylic acid and derivatives thereof having the following formula II ##STR1##...     

Relates to a composition and method for cleaning and coating metal surfaces comprising a mineral acid, a phosphoric acid concentrate having a P.sub.2 0.sub. 5 content of about 72-80% formed by heating 54% phosphoric acid with a mono- or polysaccharide, a dibasic acid such as succinic acid, thiourea and...     

A method for passivating acid-cleaned ferrous metal surfaces is disclosed. The method features the use of an aqueous passivating solution having a pH of greater than about 8, comprising a base, an oxygen containing gas, and one of hydrazine, an iron complexing agent and mixtures thereof, wherein the...     

Cleaning imaging material from a xerographic imaging surface with a cleaning blade with reduced friction between the blade and the surface is provided without image degredation by an appropriately roughened surface, which roughness is formed on the photoconductive surface by substrate pre-etching to...     

This relates to a method and solution for removing exposed photopolymer film resist from a substrate. The substrate having the photoresist thereon is contacted with a solution consisting essentially of acid selected from the group consisting of the first three carboxylic acids and their halogenated derivatives,...     

Discovery of a critical solution temperature vs acid strength profile leads to an aqueous acid-type drain opener composition consisting essentially of a solution of between about 80.8% and 84.5% by weight sulfuric acid. The composition may also contain about 0.1-0.5% by weight corrosion inhibitors, and...     

A method for preparing tungsten materials in which tungsten powder obtained by reducing tungsten oxides having doping agents added thereto is washed first with hydrochloric acid having a concentration of not lower than 4% by weight and then with hydrofluoric acid having a concentration of not lower than...     

An improved chromium-free zinc surface treatment provides for contacting the surface with an aqueous solution of a thiourea compound and a vegetable tannin at a pH value of from 2 to 6.5. Corrosion resistance and paint receptivity of the surface are enhanced.

Carboxylate cement is removed from dental products by use of a solution containing an organic acid having a COOH radical. A preferred organic acid is citric acid.

Fluorine is substituted for other halogen atoms on the 1-carbon atom of a compound which contains a 1,1,1-trihalomethyl group (trichloromethyl) by contacting said compound or a precursor thereof with liquid HF in the presence of a mixture of antimony pentahalide with a least an approximately equimolar...     

Compositions comprising mixtures of a dithiocarbamic acid derivative and a sulfonium compound such as triphenylsulfonium chloride provide effective corrosion inhibition in acid treatment of metal in the presence of a copper complexing agent such as a thiourea.

The present invention concerns a method of inhibiting or controlling calcium scale deposition in SO.sub.2 flue gas scrubbers which comprises scrubbing said flue gases with an aqueous composition comprising concentrated sodium hydroxide and a 2-hydroxyethyl iminodiacetate calcium inhibitor.

Heat transfer and associated surfaces in nuclear reactors are decontaminated by treating the surface with ozone to oxidize acid-insoluble metal oxides to a more soluble state, removing oxidized solubilized metal oxides, and removing other surface oxides using low concentrations of decontaminating reagents....     

Contaminants that accumulate on test probes utilized to contact aluminum pads on integrated circuit chips cause the probe resistance to become unacceptably high. As disclosed herein, the contaminants (predominantly a mixture of aluminum and aluminum oxide) are substantially removed by immersing the probes...     

At least a substantial amount of the corrosion products on the surface(s) of brass plated steel cord are removed by treatment in an aqueous solution containing a minor amount of an NH.sub.4, Na, K, Li, Ca, Mg, Sr, Ba and Zn salt of a saturated aliphatic carboxylic acid of from 1 to 5 carbon atoms.

A rapid and effective surface cleaning process for copper alloys, particularly copper alloys containing aluminum and other metals tending to form surface coatings of refractory oxides during annealing treatments, consists of treating such alloys or articles fabricated thereof for a short time in a hot...     

In the production of records, a mother is formed from a metal master having a nickel core and a silver coating. To produce the mother, the silver coating is removed from the nickel core and the nickel is passivated by treating the metal master with an aqueous solution containing ammonium persulphate....     

A metal finishing composition particularly useful for burnishing of metallic components while subjecting said metallic components to the action of a solid finishing media, said composition comprising an acidic burnishing media and, as a rust and discoloration inhibitor component thereof, a mixture of...     

A closed loop assembly for dissolving a layer from an article by exposing the article to a leaching solution having a predetermined boiling temperature. The assembly includes a sealed reaction container including an inner compartment to contain the leaching solution and the article, a recirculation system...     

Steel sheet is subjected to a thermal treatment as a result of which an oxide layer is formed. The sheet is pickled by contact with an organic acid solution (formic acid), containing at least 50 mg/l of iron, at a pH of 1.5 to 4 and at a temperature above a minimum value T.sub.m given by T.sub.m =20+(pH-1.5)32.

Aluminum foil, particularly for electrolytic capacitors, is degreased and deoxidized before processing by contacting the foil with a solution containing phosphoric acid and a nonionic surfactant. An agent corrosive to aluminum may be present. Contacting time is 20 to 240 seconds, and the temperature...     

An aqueous acidizer composition and method of utilizing same in the removal of scale from fresh water production equipment such as desalinators or evaporators (watermakers) and distillation units as well as heat exchangers and boilers. The composition contains a blend of three acids of varying strengths...     

A process for the removal of poly(arylene sulfide) deposits on metal surfaces is provided by contacting the deposit with at least one diaryl ether under temperature conditions and for a time sufficient to remove said poly(arylene sulfide) deposits. A process for the cleansing of metal parts having poly(arylene...     

Rust is removed from metal surfaces by applying a coating of an aqueous solution of copolymer of maleic acid and monomer. The rust becomes incorporated into the coating during drying and the coating detaches itself from the metal surface without the necessity of peeling or otherwise mechanically removing...     

The residual acid mixture containing metals which has been produced in the steel pickling process is regenerated to become new HF/HNO.sub.3 pickling acid by applying H.sub.2 SO.sub.4 addition and evaporation. The metal sulphate salt produced in evaporation is converted into scarcely soluble iron jarosite...     

A cooling system cleaning composition comprising an aqueous solution of a tetra-alkali metal salt of ethylenediaminetetraacetic acid, a soluble salt of citric acid, and a soluble salt of nitric acid. The preferred composition also contains an aluminum corrosion inhibitor and has a pH between about 10...     

A thixotropic cleaner comprising about 6 to 12% of a precipitated silica; about 0.05 to 2.5% of a cationic, nonionic or zwitterionic or amphoteric surfactant, or mixtures thereof, that has the ability to hydrogen bond and mixtures thereof; an acid; and an abrasive. The relationship between the relatively...     

A method for removing rust and/or scale from a metal surface, comprising contacting said metal surface with a homogeneous pickling solution comprising a major amount of a halogenated hydrocarbon solvent, an effective solubilizing amount of at least one alcohol solubilizer, an effective pickling amount...     

The present invention relates to a cleaning solution for removing surface oxides from copper base alloys without significantly etching the copper-base alloy material. The cleaning solution comprises from about 1 v/o to about 50 v/o hydrofluoric acid and from about 5 v/o to about 50 v/o of at least one...     

Acid-reactive organic and inorganic matter, such as stains and/or deposits, is removed from substrates by contacting such matter with a composition containing urea and sulfuric acid in which the urea/sulfuric acid molar ratio is less than 2. The urea-sulfuric acid compositions may optionally contain...     

A liquid phase cleaner-solvent consisting essentially of from about 50% to about 90% by weight of water, less than 10% by weight of sodium chloride, from about 1/2 to 1% to about 10% by weight of coconut amide, from about 1/2 of 1% to about 8% by weight of a tall oil fatty acid, from about 1% to about...     

A metal cleaning composition is provided comprising: a nonionic active agent and/or an anionic active agent having an HLB value ranging from 3 to 18; and a carboxylic acid or salt thereof represented by the formula, R--X--(CH.sub.2).sub.m --COOM in which X represents N--H, N(CH.sub.2).sub.n --COOM or...     

An acid cleaner composition to remove deposits capable of reacting with the acid and also forming thereby hydrogen sulfide, comprising from about 5 to 95% by weight of an acid having an ionization constant of at least about 1.75.times.10.sup.-5, and an effective amount of a hydrogen sulfide scavenger...     

A chemical cleaning composition consisting essentially of water, a hydroxycarboxylic acid and a peroxymonosulfate compound is useful for cleaning processing tanks used in silver halide based photographic processing systems.

A method of decontaminating radionuclide-contaminated acid insoluble corrosion products from primary system surfaces in pressurized water reactors by oxidation and concurrent dissolution in an acidic decontamination solution of the corrosion products which have been made acid-soluble by the oxidation....     

A process for the removal of deposits consisting essentially of the oxides of one or more transition metals from a surface, which process comprises contacting the said surface at a pH in the range of from 2.0 to 7.0 with a reagent comprising a one-electron reducing agent which is the complex formed between...     

Chromium free cleaning compositions for cleaning aluminum and aluminum alloy surfaces comprising A. from 0.2-4 g/l ferric ion and B. sufficient sulfuric and/or nitric acid to produce a pH of 2 or less. The invention also relates to compositions containing from 0.001-0.5 g/l of fluoride ions.

A cleaning composition bath, concentrate for its preparation, and method of use of an aqueous alkaline cleaner comprising an ethylenediaminetetraacetic acid or nitrilotriacetic acid alkali metal salt, an inorganic alkali metal phosphate, a surfactant and optionally an aluminum sequestrant, other inorganic...     

Viscous solutions of NMP are described which comprise up to about 90% NMP. The viscosifying agent is rhamsan gum.

A method is set forth of treating the surface of an object such as a semiconductor wafer to remove impurities. In particular, the method serves to strip resist in a short period of time, of the order of 30 seconds. The object is positioned with the surface exposed within a treating chamber. Water vapor...     

Corrosion inhibiting compositions for addition to aqueous acid metal cleaning compositions for use in the cleaning of surfaces of metal parts which are contaminated with water insoluble, acid soluble deposits, wherein the corrosion inhibiting composition contains a partially hydrolyzed protein which...     

A rust converting composition comprises ascorbic acid, lignin sulfonate, and a water insoluble polymer, such as polyvinylpyrrolidone, and optionally a thickener. The invention further provides a method for removing rust from rusted metal surfaces by applying the composition, allowing the composition...     

A process for koshering relatively large metallic containers used to store and transport kosher foods includes the steps of washing and rinsing the interior of the container with kosher-approved compounds to remove surface oils and greases, treating the interior surface of the container with a kosher-approved...     

A process for removing radioactive species such as technetium from surfaces of components such as those formed from aluminum, and a process of treating the resulting effluents. For example, technetium trapped under an oxide layer present on an aluminum component is removed by removing the oxide layer...     

Aqueous acid cleaning compositions well adapted, e.g., for the descaling of metallic face surfaces include (i) water, (ii) a carboxylic acid dissolved therein having a dissociation constant pK, at 25.degree. C., of at least 2, (iii) a stabilizing amount of at least one salt of an acid having a pK value...     

The present invention offers a cleaning agent for aluminium surface which is an aqueous acidic liquid containing peroxo acid and/or peroxide in 0.05-10 g/l and further one or more kinds out of sulphuric acid, phosphoric acid and nitric acid.

Smut may be removed from the surface of aluminum or aluminum alloys by a deoxidizer comprising nitric acid, a halate salt, and, optionally, an activator.

Chromium free cleaning compositions for cleaning aluminum and aluminum alloy surfaces comprising A. from 0.2-4 g/l ferric ion and B. sufficient sulfuric and/or nitric acid to produce a pH of 2 or less. The invention also relates to compositions containing from 0.001-0.5 g/l of fluoride ions.

A process for koshering relatively large metallic containers used to store and transport kosher foods includes the steps of washing and rinsing the interior of the container to remove surface oils and greases, treating the interior surface of the container with a rust inhibitor, flame treating the interior...     

A composition and process for cleaning an aluminum-containing article is disclosed. The process comprises: contacting a debris-laden aluminum containing article with a composition at conditions effective to do at least one of the following: (1) remove at least a portion of the debris from the aluminum-containing...     

A chemical polishing bath and process are disclosed for pretreating aluminum and its alloys prior to plating or anodizing operations, which bath and process produce a mirrorlike finish.

A composition and process for cleaning an aluminum-containing article is disclosed. The process comprises contacting a debris-laden aluminum-containing article with a composition at conditions effective to do at least one of the following: (1) remove at least a portion of the debris from the aluminum-containing...     

A new superabsorber which gels and cross-links as hydrated has been developed. The superabsorber contains a branched-chain polyanionic carbohydrate such as carboxymethylcellulose, a cross-linking agent, and a hydrophobic carboxylic acid. The superabsorber is biodegradable and non-toxic.

Perhalogenated compounds, such as perfluorinated surfactants, for inclusion in aqueous systems, are provided in a cosolvent system consisting essentially of one or more acidic phosphorous-containing compounds selected from phosphoric or phosphorous acids, water-soluble di- or polyphosphonic or phosphinic...     

Aqueous mixed permonosulphuric acid/sulphuric acid solutions, such as semiconductor surface photoresist stripping solutions may be stabilised for storage by the addition of one or more of the metals gallium, germanium, indium, tin in the 4-valent form, antimony, thallium, bismuth and lead suitably in...     

A improved projector lamp with an internal reflector may be made by forming the reflector from pure aluminum, or an aluminum alloy not including amounts of vaporizable materials. Anodized aluminum is not used. A pure aluminum reflector is mechanically polished and chemically etched to attain a high level...     

An acid soluble mercury metal salt intensifier is provided to inhibit corrosion in conjunction with a corrosion inhibitor when a steel surface is present in an acid environment. The mercury metal salt may be a mercuric halide, such as mercuric chloride or may be a mercuric acetate, mercuric oxide, mercuric...     

A method of removing iron contaminants in an aqueous system by introducing and maintaining within the system at least one ortho dihydroxyaromatic compound having at least one electron withdrawing group pendant from the aromatic ring and, further, a method of inhibiting calcium scale formation in the...     

A process for koshering relatively large metallic containers used to store and transport kosher foods includes the steps of washing and rinsing the interior of the container to remove surface oils and greases, treating the interior surface of the container with a rust inhibitor, flame treating the interior...     

This invention relates to a cleansing composition comprising a detergent and an acid salt and/or a complex of formic acid which has more than one chemical equivalent of formate ion per cation other than hydrogen. The compositions are suitable for cleaning stains and iron oxide deposits caused by the...     

A system for cleaning radiator systems waste coolant, including a filter, a flush tank refinery, a source of cleansing chemical, a pump to circulate radiator coolant from the vehicle through the cleaning system back to the vehicle, a quick-connect conduit extending between the vehicle and the filter,...     

A positive photoresist stripper composition includes a solvent system having solubility parameters which fall within a range from about 8.5 to about 15 in an amount which falls within a range from about 65% to about 98%. An amine is present in an amount which falls within a range from about 2% to about...     

A method for cleaning a vessel by dissolving iron oxide present in the vessel includes introducing a saline solution into the vessel, the saline solution being formed of an acid acting as a complexing agent, of an alkalizing agent and of a reducing agent, the saline solution acting as an alkaline reducer;...     

A liquid concentrate composition for use in the cleaning of a surface comprises a mixture of sodium di-isopropyl naphthalene sulfonate, trisodium nitrilotriacetate and sodium diethanolglycinate.

An improved method for rapidly stripping solder or tin from a substrate, such as copper, without adversely affecting the substrate. This is especially useful in the preparation of printed circuit boards. The composition comprises an acidic solution of an iron salt, a nitrate, at least one complexing...     

An acid-based cleaner and related methods, for cleaning and treating tile, limestone-based cement and concrete and similar surfaces to maintain a slip-resistant surface, and to harden and strengthen the grout or cement and make it more resistant to penetration by salt or other deterious chemicals. The...     

A method for cleaning a vessel by dissolving iron oxide present in the vessel includes introducing a saline solution into the vessel, the saline solution being formed of an acid acting as a complexing agent, of an alkalizing agent and of a reducing agent, the saline solution acting as an alkaline reducer;...     

A process for preparing a stainless steel surface for bonding to an adhes is described. First, the surface is wiped with a solvent and then soaked in an alkaline bath at an elevated temperature to remove dirt and grease. The surface is then rinsed with water and immersed in a 135-.degree.F. to 145-.degree.F....     

A lubricating agent for a burnishing compound comprising an aqueous solvent, an alkyl betaine that is soluble in the aqueous solvent, and a nonchelating acid that is soluble in the aqueous solvent. The alkyl betaine is of the formula: ##STR1## wherein R, R.sub.1, R.sub.2 are organic radicals that are...     

The novel heteropolysaccharide BM07, useful, e.g., as a thickening/stabilizing/suspending agent for a wide variety of industrial applications, is produced by fermenting a nutrient medium containing at least one source of assimilable carbon with a strain of Agrobacterium tumefaciens I-736, or recombinant...     

The invention relates to a method for cleaning a semiconductor product of particles accumulated on its surface and of metallic and organic contamination. According to the invention, the washing of the semiconductor product is carried out with an acid-water solution with a dilution ratio between 1:10.sup.6...     

A hydrochloric acid pickling accelerator for batch and continuous hydrochloric acid pickling baths for all types of steel, comprising an admixture of from about 10 to about 15 percent by weight glycol, from about 20 to about 30 percent by weight calcium chloride, from about 3 to about 6 percent by weight...     

The present invention relates to a composition and method for opening clogged drains. Specifically, the liquid drain opener composition of the present invention comprises about 70%-93% by weight sulfuric acid; about 1%-23% by weight water; about 0.01%-5% by weight of at least one corrosion inhibiting...     

Strong acid cleaning compositions supplemented with stable, protein-reactive staining dyes are provided which can be used for the acid clean-up of metallic food processing equipment while also giving a visual indication of residual soils on equipment surfaces. The compositions are provided as dilutable...     

A method and composition for cleaning aluminum surfaces is disclosed. The surfaces are contacted with a treatment comprising potassium hydroxide, a silicate compound and an alkyl imino acid surfactant.

Aqueous compositions comprising certain amino acids such as polyaspartic acid or aspartic acid/glutamic acid copolymers when at least partially protonated at pH of 7 or below effectively clean ferrous metal surfaces by contacting said surfaces with said compositions.

A method and composition for removing hardened concrete from surfaces on trucks, mixers, and other equipment used in the concrete industry. The cleaning composition includes hydroxyacetic acid, a soap agent, and a degreasing agent mixed together in an aqueous solution. In the preferred embodiment, the...     

In a cleaning method, two kinds of cleaning solutions, one of which is acid solution of about pH 2 or less (first cleaning solution) and other of which is acid solution of about pH 3 to 4 (second cleaning solution), are successively used to clean a semiconductor substrate. In a first cleaning step, the...     

Used or partially used orthopaedic implants or similar medical devices which have been in contact with animal tissue are decontaminated and made available for reuse by a three step process effective for removal of protein tissue, bone tissue, and lipids.

A process for cleaning a surface contaminated with an organic, acidic or basic contaminant. In the process, a liquid-state composition including an agent selected form the group consisting of an absorbant, an acid-neutralizing agent and a base-neutralizing agent is applied to the surface, and allowed...     

A solution and solution concentrate for cleaning metal surfaces, particularly aluminum surfaces in which CaO or Ca (OH).sub.2 is added to sulfuric acid to raise the pH to about 13.1 after which the solution is passed through an eleven micron filter and potassium hydroxide is added to raise the pH to...     

The present invention provides a method of removing lead oxide from a surface having lead oxide deposited thereon. The method includes contacting the article containing lead contaminated with radioactive material with a decontamination composition comprising about 0.01 to 5 percent, by weight, of a reductant,...     

A method for maximizing electrical contact between contact surfaces, consisting essentially of a volatile cleaning agent and an oxidation occluding agent. The method uses an applicator device for cleaning and protecting electrical contact surfaces utilizing this composition.

Semiconductor wafers are positioned in a cleaning tank and subjected to sequential flows of one or more highly diluted cleaning solutions that are injected from the lower end of the tank and allowed to overflow at the upper end. One solution contains one part ammonium hydroxide, two parts hydrogen peroxide,...     

The present invention provides a method of decontaminating an article containing lead contaminated with radioactive material. The method includes contacting the article containing lead contaminated with radioactive material with a decontamination composition comprising about 0.01 to 5 percent, by weight,...     

The present invention provides a method for cleaning a silicon wafer with a cleaning fluid, comprising 35 to 65% by weight of HNO.sub.3, 0.05 to 0.5% by weight of HF, 0.05 to 0.5% by weight of HCl, 0.002 to 0.1% by weight of a surface-active agent, and water. The silicon wafer cleaning method involves...     

Alkaline earth metal scales, particularly barium sulfate and strontium sulfate, and silica-based scales, particularly potassium fluorosilicate, are removed from industrial processing equipment, tubular goods, and other scaled materials with a composition comprising sufficient potassium base to provide...     

An aqueous and acidic stripping and cleaning composition is provided which contains a polyhydric alcohol, ammonium fluoride, dimethylsulfoxide and water. The pH of the composition is greater than about 4 but less than 7. Also provided is a method of stripping and cleaning utilizing the compositions of...     

A method is provided for removing metal oxide debris from various types of surfaces, both metallic and nonmetallic. Specifically, the surface to be cleaned is treated (preferably by immersion) with a preheated solution of 65 to 71 wt % (55.3 to 62.0 vol %) nitric acid, which is roughly equivalent to...     

A metal cleaning composition comprising EDDS is described. Preferably, the compositions comprise optical isomers of EDDS, such as (s,s)EDDS. The compositions are particularly well suited for cleaning iron, zinc, aluminum, and copper. De-icer compositions comprising EDDS are also described. Also disclosed...     

A pickling method which can effectively conduct pickling, and can shorten pickling time. The strip is plastic elongated by 0.1 to 10% before it is introduced into the pickling tank to form cracks. The strip is bent so that a surface strain of the strip is 0.2 to 1 times the plastic elongation during...     

The present invention relates to formulations and methods for preventing surfaces of natural or mineral materials or cementitious products from becoming slippery, especially when wet. The formulations comprise a non-fluorine-containing acid; a fluorine-containing compound, hydrogen sulfate or acetic...     

A method for treating and maintaining floors cleans the floor and restores an optimum coefficient of friction. The method involves a restoring phase and a cleaning phase, in which the cleaning phase is performed using the same solution as in the restoring phase, but in a diluted form. The method is applicable...     

A copper surface pickling process is improved by providing most of the oxidizing agent (such as hydrogen peroxide) used in the process in a separate bath following a primarily acid bath. The temperature of the separate hydrogen peroxide bath can be kept lower, which reduces hydrogen peroxide loss and...