A nail cleanser containing sodium ethylenediamine tetraacetic acid, urea and water. When applied to nails it removes various stains such as tobacco, nail pigment, shoe polish, furniture polish and hair dyes.
2. A nail cleanser as set forth in claim 1 wherein the first chelating agent being present in an amount of from about 1 percent to about 3 percent by weight of the liquid cleanser, the second chelating agent being present in an amount of from about 4 percent to about 6 percent by weight of the nail cleanser, and the liquid carrier being present in an amount of from about 70 percent to about 80 percent of the liquid cleanser, said liquid cleanser further including optional ingredients making up the balance of the weight and comprising one or more mild abrasives, a one or more texturizing agents, one or more thickener, one or more solubilizing agents, one or more preservatives and one or more fragrances.
3. A nail cleanser as set forth in claim 2 wherein the mild abrasive is selected from the group consisting of silica, diatomaceous earth and talc, wherein the texturizing agent is selected from the group consisting of hydrolized animal protein, laneth 10-acetate and sorbitan sesquioleate, wherein the thickener is selected from the group consisting of cellulose gum, hydroxy ethyl cellulose, Irish moss, tragacanth, mucilage, and alkali metal salts of polyacrylic acid, wherein the solubilizing agent is selected from the group consisting of propylene glycol and ethylene glycol and wherein the preservative is selected from the group consisting of methyl paraben and ethyl paraben.
4. A nail cleanser as set forth in claim 3 wherein a mild abrasive is present in an amount up to about 5 percent of the weight of the cleanser, a texturizing agent is present in an amount up to about 10 percent by weight of the cleanser, a thickener is present in an amount up to about 3 percent by weight of the cleanser, a solubilizing agent is present in an amount up to about 25 percent by weight of the cleanser, a preservative is present in an amount up to about 0.6 percent by weight of the cleanser and a fragrance is present in an amount up to about 0.5 percent by weight of the cleanser.
5. A nail cleanser as set forth in claim 4 having the following formulation:
______________________________________
MAXIMUM
RANGE BY WEIGHT
INGREDIENTS OF NAIL CLEANSER
______________________________________
Water 40-80%
Disodium EDTA 1-30%
Silica 0-5%
Hydrolyzed Animal Protein
0-2%
Laneth-10 Acetate 0-10%
Acetone 0-20%
Sorbitan Sesquioleate
0-5%
Cellulose Gum 0-3%
Urea 1-30%
Propylene Glycol 5-25%
Methyl Paraben 0.10-0.50%
Propyl Paraben 0.03-0.10%
Fragrance 0.0-0.5%
______________________________________
6. A nail cleanser as set forth in claim 4 having the following formulation:
______________________________________
IDEAL RANGE
INGREDIENTS BY WEIGHT
______________________________________
Water 70-80%
Disodium EDTA 1-3%
Silica 1-3%
Hydrolyzed Animal Protein
0.10-0.50%
Laneth-10 Acetate 1-3%
Acetone 4-6%
Sorbitan Sesquioleate
1-3%
Cellulose Gum 1-3%
Urea 4-6%
Propylene Glycol 4-6%
Methyl Paraben 0.10-0.20%
Propyl Paraben 0.04-0.06%
Fragrance 0.1-0.3%
______________________________________
7. A nail cleanser as set forth in claim 4 having the following formulations:
______________________________________
PERCENTAGE BY WEIGHT
INGREDIENTS OF THE NAIL CLEANSER
______________________________________
Water 76.05
Disodium EDTA 2.00
Silica 1.50
Hydrolyzed Animal Protein
0.10
Laneth-10 Acetate
2.00
Acetone 4.50
Sorbitan Sesquioleate
1.50
Cellulose Gum 2.00
Urea 5.00
Propylene Glycol 5.00
Methyl Paraben 0.10
Propyl Paraben 0.05
______________________________________
Description
U.S. Pat. No. 3,694,366
U.S. Pat. No. 3,708,437
U.S. Pat. No. 3,957,967
U.S. Pat. No. 4,115,293
SUMMARY OF THE INVENTION
Purpose of the Invention
It is an object of the invention to provide a nail cleansing composition of the character described which is simple and inexpensive and which upon application to the nails and removal within a short period of time will remove stains.
It is another object of the invention to provide a nail cleanser of the character described which is easy to use and requires no special instructions for its application.
It is another object of the invention to provide a nail cleanser of the character described which leaves the nails in good condition to receive subsequent application of nail cosmetics such for instance as clear or opaque nail polishes.
It is another object of the invention to provide a nail cleanser of the character described which has no detrimental effects on the nails, the cuticles or the adjacent skin.
It is another object of the invention to provide a nail cleanser of the character described which is non-allergenic and non-toxic.
It is another object of the invention to provide a nail cleanser of the character described which includes chelating agents as necessary ingredients and which further includes conventional cosmetic additives such as thickeners, preservatives, texturizing agents and abrasives.
It is another object of the invention to provide a nail cleanser of the character described which does not include among its ingredients any unstable or potentially explosive chemicals such as oxidizers.
Other objects of the invention in part will be obvious and in part will be pointed out hereinafter.
BRIEF DESCRIPTION OF THE INVENTION
The nail cleanser of the present invention is characterized by the inclusion of essential ingredients present within prescribed critical ranges, by the further necessary inclusion of a liquid carrier for these ingredients and by the optional inclusion of various additives whose presence, although desirable for maximum efficiency of the cleanser, for ease of use and for various cosmetic and odoriferous purposes, is not essential. The necessary ingredients are: Firstly, a particularly effective chelating agent and secondly a chemical which is a milder chelating agent and desirably also is a solubilizing agent. Specifically the first chelating agent, i.e. the one having the higher effectiveness, is selected from a group consisting of ethylenediamine tetraacetic acid, phytol, phytic acid, nitrilo-triacetic acid, diethylene triamino pentaacetic acid, sodium tripolyphosphates and metaphosphate, sodium hexamethaphosphate, trisodium phosphate and ethylene diamino tetraacetic acid. The preferred first chelating agent is an alkali metal salt of ethylenediamine tetraacetic acid, for example sodium ethylenediamine tetraacetic acid. For the second, i.e. milder, chelating agent urea is employed or a substitute therefor, such as allantoin, penthenol and aloe vera extract.
Although the present invention is not to be so limited it is believed that the new cleansing agent acts on stains in nails by complexing the metal ions that are present in most stains and thereby rendering the stain leuco, i.e. colorless. The metal ions thus extracted become solubilized by the chelating agent and thereupon form a soluble ingredient of the cleansing agent. Subsequently they leave the nail with the cleansing agent when the cleansing agent is removed. The second, i.e. milder, chelating agent is believed to assist in the extraction and solubilization of the metal ions and in general to exert a solubilizing effect on organic staining material so as to aid in removing it from the nails.
The liquid carrier is of course a necessary ingredient. Various liquid carriers can be used and desirably they are such that the first and second necessary ingredients are soluble or dispersible and suspendable therein. Typical acceptable liquid carriers are water, liquid alcohols and acetone. In general the liquid carrier desirably is inexpensive and water therefore is the carrier of choice.
The critical range for the first chelating agent is from about 1 percent to about 30 percent by weight of the nail cleanser. The critical range for the second chelating agent is from about 1 percent to about 30 percent by weight of the nail cleanser. The critical range for the liquid carrier is from about 40 percent to about 80 percent by weight of the nail cleanser. The preferred ranges for these three constituents are: for the first chelating agent about 1 percent to about 3 percent, for the second chelating agent from about 4 percent to about 6 percent and for the liquid carrier from about 70 percent to about 80 percent of the cleanser.
The foregoing three constituents are the constituents of which the liquid carrier essentially consists.
In addition to the essential constituents there are as mentioned earlier a number of desirable additives, for example a mild abrasive such as silica, diatomaceous earth and talc in an amount up to about 5 percent, preferably from about 1 to about 3 percent of the cleanser, to improve the texture hydrolized animal protein up to 2 percent, and preferably from about 0.1 percent to about 0.5 percent of the cleanser, laneth-10 acetate up to about 10 percent, preferably from about 1 percent to about 3 percent of the cleanser and sorbitan sesquioleate up to about 5 percent, preferably from about 1 percent to about 3 percent of the cleanser, a thickener such as cellulose gum, hydroxy ethyl cellulose, Irish moss, tragacanth and other mucilages, and alkali metal salts of polyacrylic acid up to about 3 percent and preferably from about 1 percent to about 3 percent of the cleanser, a solubilizing agent for the various constituents in the liquid carrier such as propylene glycol and ethylene glycol, these materials being particularly desirable constituents and being present in an amount between about 5 percent and about 25 percent, desirably between about 4 percent and about 6 percent of the cleanser; a preservative such as methyl paraben and propyl paraben, the methyl paraben being present in an amount from about 0.10 percent to about 0.5 percent of the cleanser, desirably from about 0.10 percent to about 0.20 percent by weight of the cleanser, the propyl paraben being present in an amount of from about 0.04 percent to about 0.10 percent, desirably from about 0.04 percent to about 0.06 percent of the cleanser, and a fragrance, typically up to 0.5 percent of the cleanser and desirably from about 0.1 percent to about 0.3 percent of the cleanser. All percentages mentioned are by weight.
DESCRIPTION OF THE PREFERRED EMBODIMENT
As mentioned above, certain components of the nail cleanser necessarily are present, others are optional. The necessary components are a first chelating agent which is a relatively active one, its activity being in comparison to the activity of a second chelating agent which is the second necessary ingredient of the nail cleanser formulation. The third necessary ingredient is a liquid carrier for the first chelating agent and for the second chelating agent. The second chelating agent also functions as a solubilizing agent for various constituents of the nail cleanser.
The optional ingredients are ingredients which are conventionally employed in many other cosmetic formulations for well known functions. These include: one or more mild abrasives, one or more texturizing agents, one or more thickeners, one or more solubilizing agents in addition to the second chelating agent, oen or more preservatives and one or more fragrances.
For the first chelating agent the material of choice is ethylene diamine tetraacetic acid and in particular an alkali metal salt thereof. Other compounds that can be used for the first chelating agent are: phytol, phytic acid, nitrilo-triacetic acid, diethylene triamino pentaacetic acid, sodium tripolyphosphates, sodium metaphosphate, sodium hexamethaphosphate, trisodiumphosphate and ethylene diamino tetraacetic acid. The preferred second ingredient, i.e. the milder chelating agent is urea. Other milder chelating agents which can be used in place of the urea are: allantoin, d-penthenol, aloe vera extract and urea precursors.
The third and last necessary ingredient is a liquid carrier which will solvate or disperse the sundry ingredients of the nail cleanser. The preferred carrier is water since it will perform the function required and is the least costly. In place of or in addition to water, liquid alcohols or acetone can be used.
Insofar as the optional constituents are concerned they constitute the following:
A mild abrasive such as silica, diatomaceous earth and talc.
A texturizing material such as a hydrolized animal protein, laneth-10 acetate and sorbitan sesquioleate.
A thickener such as cellulose gum, hydroxy ethyl cellulose,Irish moss, tragacanth, mucilage and alkali salts of polyacrylic acid.
A solubilizing agent such as propylene glycol and ethylene glycol.
A preservative such as methyl paraben and propyl paraben.
A fragrance.
The preferred optional materials that are employed are silica, hydrolized animal protein, laneth-10 acetate, sorbitan sesquioleate, cellulose gum, glycol, methyl paraben, propyl paraben and a fragrance. In addition it is desirable also to include a small amount of acetone to assist in solubilization.
Set forth below is a preferred formulation for a nail cleanser embodying the invention.
______________________________________
PERCENTAGE BY WEIGHT
INGREDIENTS OF NAIL CLEANSER
______________________________________
Water 76.05
Disodium EDTA 2.00
Silica 1.50
Hydrolyzed Animal Protein
0.10
Laneth-10 Acetate
2.00
Acetone 4.50
Sorbitan Sesquioleate
1.50
Cellulose Gum 2.00
Urea 5.00
Propylene Glycol 5.00
Methyl Paraben 0.10
Propyl Paraben 0.05
______________________________________
It will be understood that the invention is not restricted to the particular compounds listed above inasmuch, as mentioned previously, different ingredients may be substituted for the ones listed; moreover the formulation can be varied considerably and to indicate the range of variations there are set forth below the ideal range by weight and the maximum range by weight for each of the mentioned ingredients.
______________________________________
MAXIMUM
RANGE BY WEIGHT IDEAL RANGE
INGREDIENTS OF NAIL CLEANSER
BY WEIGHT
______________________________________
Water 40-80% 70-80%
Disodium EDTA
1-30% 1-3%
Silica 0-5% 1-3%
Hydrolyzed
Animal Protein
0-2% 0.10-0.50%
Laneth-10 Acetate
0-10% 1-3%
Acetone 0-20% 4-6%
Sorbitan
Sesquioleate
0-5% 1-3%
Cellulose Gum
0-3% 1-3%
Urea 1-30% 4-6%
Propylene Glycol
5-25% 4-6%
Methyl Paraben
0.10-0.50% 0.10-0.20%
Propyl Paraben
0.03-0.10% 0.04-0.06%
Fragrance 0.0-0.5% 0.1-0.3%
______________________________________
The pH of the nail cleanser should range between about 6 and about 8 and preferably is substantially neutral, that is to say 7.
The nail cleanser is used simply by applying it to a nail, after the removal of nail polish if present, leaving the cleanser on for a short period, for example about ten seconds to about one half minute, and wiping it off with a rag. It is not necessary to clean off any residue. The small amount of acetone in the cleanser will remove any trace of nail polish that is present.
The viscosity of the nail cleanser can vary quite widely. The only critical factor is that it be sufficient viscous to remain on the nail for a time sufficient to remove the stain, such time having been indicated above.
A typical satisfactory viscosity is 11,000 cps in which form it is a cream.
A study performed on a 100 subjects showed generally excellent results. In the study the preferred nail cleanser formulation was used. It was applied to the nails with a brush after removal of nail polish and left on between about a quarter to half a minute. The nails of people of various ages were cleaned in the aforesaid manner. All the nails of each subject were thus treated. In some instances the nail cleanser was applied more than once. Set forth below are the results of the study:
__________________________________________________________________________
SUBJECT HOW MANY
NUMBER
AGE TYPE OF STAIN APPLICATIONS
RESULTS
__________________________________________________________________________
1 53 Nail Pigment(Yellow stain)
4 Excellent
2 52 Nail Pigment(Yellow stain)
2 Excellent
3 52 Nail Pigment(Yellow stain)
2 Excellent
4 49 Shoe polish 4 Excellent
5 37 Nail pigment(Yellow stain)
1 Excellent
6 43 Tobacco stain 1 Excellent
7 39 Nail pigment(Yellow stain)
2 Excellent
8 40 Nail pigment(yellow stain)
2 Excellent
9 34 Nail pigment(yellow stain)
1 Excellent
10 34 Nail pigment(yellow stain)
4 Excellent
11 34 Nail pigment(yellow stain)
2 Excellent
12 34 Nail pigment(yellow stain)
1 Excellent
13 38 Nail pigment(yellow stain)
1 Excellent
14 31 Nail pigment(yellow stain)
3 Excellent
15 31 Nail pigment(yellow stain)
2 Excellent
16 34 Tobacco stain 1 Excellent
17 30 Nail pigment(yellow stain)
2 Excellent
18 30 Nail pigment(tobacco stain)
1 Excellent
19 39 Tobacco stain/shoe polish
2 Excellent
20 40 Tobacco stain/shoe polish
2 Excellent
21 36 Tobacco stain/furniture polish
1 Excellent
22 27 Nail pigment(yellow stain)
1 Excellent
23 30 Nail pigment(yellow stain)
1 Excellent
24 27 Tobacco stain 2 Excellent
25 58 Nail pigment(yellow stain)
1 Excellent
26 62 Nail pigment(yellow stain)
1 Excellent
27 36 Nail pigment/tobacco stain
2 Excellent
28 22 Nail pigment(yellow stain)
1 Excellent
29 52 Dye 1 Excellent
30 62 Nail stain/tobacco stain
1 Excellent
31 49 Iodine/shoe polish/tobacco
3 Excellent
32 53 Nail pigment(yellow stain)
1 Excellent
33 54 Nail pigment(yellow stain)
1 Excellent
34 47 Nail pigment(yellow stain)
2 Excellent
35 47 Nail pigment(yellow stain)
1 Excellent
36 55 Nail pigment(tobacco stain
3 Excellent
37 47 Other 1 Excellent
38 55 Nail pigment/tobacco stain
4 Excellent
39 50 Shoe polish 1 Excellent
40 38 Nail pigment/tobacco stain
4 Excellent
41 14 Nail pigment(yellow stain)
1 Excellent
42 35 Nail pigment/tobacco stain
1 Excellent
43 33 Nail pigment/tobacco stain
2 Excellent
44 36 Nail pigment(yellow stain)
2 Excellent
45 46 Nail pigment(yellow stain)
2 Excellent
46 66 Tobacco stain 1 Excellent
47 37 Furniture stain
1 Excellent
48 21 Hair dye 2 Excellent
49 30 Nail pigment(yellow stain)
1 Excellent
50 28 Nail pigment/tobacco stain
1 Excellent
51 41 Shoe polish 1 Excellent
52 51 Nail pigment(yellow stain)
2 Excellent
53 43 Nail pigment(yellow stain)
1 Excellent
54 39 Nail pigment(yellow stain)
1 Excellent
55 48 Nail pigment(yellow stain)
2 Excellent
56 55 Nail pigment(yellow stain)
2 Excellent
57 53 Nail pigment(yellow stain)
1 Excellent
58 53 Nail pigment(yellow stain)
1 Excellent
59 33 Nail pigment(yellow stain)
2 Excellent
60 47 Nail pigment(yellow stain)
1 Excellent
61 52 Nail pigment(yellow stain)
1 Excellent
62 57 Nail pigmen/tobacco stain
4 Excellent
63 32 Tobacco stain 1 Excellent
64 34 Tobacco stain 1 Excellent
65 26 Nail pigment/tobacco stain
2 Excellent
66 24 Nail pigment(yellow stain)
1 Excellent
67 35 Nail pigment(yellow stain)
4 Excellent
68 29 Nail pigment(yellow stain)
1 Excellent
69 35 Tobacco stain 1 Excellent
70 37 Nail pigment(yellow stain)
2 Excellent
71 45 Nail pigment(yellow stain)
4 Good-slight
yellow tinge
remained on
4 fingers
72 34 Nail pigment/tobacco stain
3 Excellent
73 47 Nail pigment(yellow stain)
4 Good-slight
yellow tinge
remained on
5 fingers
74 56 Nail pigment(yellow stain)
1 Excellent
75 59 Nail pigment(yellow stain)
1 Excellent
76 44 Nail pigment(yellow stain)
1 Excellent
77 50 Nail pigment(yellow stain)
1 Excellent
78 39 Nail pigment(yellow stain)
1 Excellent
79 53 Tobacco stain 2 Excellent
80 31 Nail pigment(yellow stain)
1 Excellent
81 36 Nail pigment(yellow stain)
1 Excellent
82 14 Nail pigment(yellow stain)
1 Excellent
83 54 Nail pigment(yellow stain)
5 Good-slight
stain re-
mained on all
fingers
84 18 Nail pigment/tobacco stain
1 Excellent
85 22 Nail pigment/tobacco stain
1 Excellent
86 47 Tobacco stain 2 Excellent
87 57 Nail pigment(yellow stain)
1 Excellent
88 29 Nail pigment(yellow stain)
1 Excellent
89 39 Nail pigment(yellow stain)
1 Excellent
90 37 Nail pigment(yellow stain)
1 Excellent
91 24 Nail pigment(yellow stain)
1 Excellent
92 21 Nail pigment/tobacco stain
1 Excellent
93 27 Tobacco stain 1 Excellent
94 25 Nail pigment(yellow stain)
1 Excellent
95 22 Nail pigment(yellow stain)
1 Excellent
96 25 Tobacco stain 1 Excellent
97 26 Nail pigment(yellow stain)
1 Excellent
98 24 Nail pigment(yellow stain)
1 Excellent
99 28 Nail pigment(yellow stain)
1 Excellent
100 23 Tobacco stain 1 Excellent
__________________________________________________________________________
It thus will be seen that there has been provided a nail cleanser which achieves the various objects of the invention and is well adapted to meet the conditions of practical use.
As various possible embodiments might be made of the above invention, and as various changes might be made in the embodiment above set forth it is to be understood that all matter herein described is to be interpreted as illustrative and not in a limited sense.
