Organic material is resin or resinous

Improved cementing compositions and their use in well cementing operations is disclosed, wherein methacrylamidopropyltrimethylammonium chloride polymers are used as fluid loss additives for aqueous hydraulic cement slurries.

A water-insoluble particulate composition having controlled slow oil-solubility at temperatures in excess of 350.degree. F. is disclosed. The composition is comprised of solid particles of a homogeneous mixture of (1) polyethylene, ethylene-vinyl acetate copolymer containing about 15 to 30 weight percent...     

An epoxy resin composition curable to a hard impermeable solid which contains a liquid aromatic diluent having the general formula: C.sub.6 (R.sub.1).sub.6 wherein R.sub.1 is hydrogen; a straight or branched chain alkyl radical; a cycloparaffin radical or a mixture thereof; wherein the alkyl and cycloparaffin...     

In a method wherein two or more separate zones in a single wellbore are subjected to a consolidation treatment to prevent the production of solid particles from those zones into the wellbore, a tracer material is incorporated into each zone which is subjected to the consolidated treatment, the tracer...     

A process using discrete solid particles of polyvinyl acetate as diverting agents in acid treating subterranean geological formations penetrated by a well.

A method for stimulating an unconsolidated formation in a well wherein the unconsolidated formation is fractured in the unconsolidated state, i.e., without having had any prior consolidation treatment practiced thereon, the fracturing step employing a propping agent, and consolidating essentially only...     

A method of controlling the migration of fines in a subterranean formation comprising contacting the formation with a dilute resin solution; displacing the resin solution into the formation, preferably with an overflush oil, so as to leave behind a thin film of resin solution; extracting the diluent...     

The invention relates to a soil stabilization composition comprising a rubber latex of solids content at least 40% by weight and a compatible oil which is prepared by admixing the oil and the latex in the presence of additional emulsifier and in the substantial absence of added water. The composition...     

Loose particles are consolidated, e.g., to prevent them from falling into well bores in producing wells, by contacting the loose particles with a solution having a pH above 7 containing water-soluble polymer, e.g., polyvinyl alcohol and hydroxyethyl cellulose, and a polyisocyanurate salt and maintaining...     

A composition of matter comprising water, a polymer capable of being crosslinked by polyvalent metal cations, a reducible species containing said polyvalent metal in a higher oxidation state, and a reducing agent selected from among KI, MnCl.sub.2, Mn(NO.sub.3).sub.2, and K.sub.4 Fe(CN).sub.6 which composition...     

A method is provided for reducing the water permeability of a porous subterranean formation by injecting a dispersion of polyamide and a water soluble polymer through a well bore into the formation. Preferred materials are polyamides and poly-acrylamides.

An epoxy resin composition curable to a hard impermeable solid which contains a liquid aromatic diluent having the general formula: C.sub.6 (R.sub.1).sub.6 wherein R.sub.1 is hydrogen; a straight or branched chain alkyl radical; a cycloparaffin radical or a mixture thereof; wherein the alkyl and cycloparaffin...     

Method for the treatment of unconsolidated sandy formations to stabilize such formation comprising the sequential steps of: 1. Injecting a liquid hydrocarbon containing a minor amount of a water wetting nonionic surface active agent and, from about 0.5 to about 3% of water, into said formation to remove...     

Method of and composition for the treatment of unconsolidated sandy formations to stabilize the formation comprising injecting a treating composition consisting essentially of, on a volume basis, 10 to 25% of furfuryl alcohol, 1-4% of a nonionic dispersing surfactant, 1-4% of water, 0.5-1.5% of a silane...     

A treating process is provided for increasing the stability and resistance to degradation of naturally or artificially consolidated, permeable masses such as earthen formations or subterranean formations having exposed siliceous surfaces which are contacted by aqueous media. The treatment is effected...     

Processes for plugging oil producing formations, fluid thief formations and the like in oil wells and compositions for the same are disclosed.

Method of completing a hydrocarbon containing formation located downhole in a cased borehole by running a jet perforating gun downhole on the end of a tubing string. The tool string includes a vent assembly underlying a packer and located above the gun. The gun includes a special flexible linkage and...     

A method of stabilizing soil, such as sub-bases, bases and wear courses of roads and airport runways, sand dunes and other loose, particulate material, which includes mixing an epoxy resin ester of unsaturated fatty acids with soil, preferably at the optimum moisture content of the soil, in ratios of...     

The present invention relates to a process for the reinforcement of geological formations and loose rock and earth masses by introducing, into the cavities of the geological formations or rock or earth masses which are required to be reinforced, reaction mixtures based on organic polyhydroxyl compounds...     

Method of and composition for the treatment of unconsolidated sandy formations to stabilize the formation comprising injecting a treating composition consisting essentially of, on a volume basis, 10 to 25% of furfuryl alcohol, 1-4% of a nonionic dispersing surfactant, 1-4% of water, 0.5-1.5% of a silane...     

Superficial aggregate material (e.g. soil, sand) is consolidated by means of a water-insoluble, moisture-curable NCO-terminated prepolymer having defined physical properties.

There is disclosed an aqueous medium comprising water to which has been added a water thickening amount of a water thickening polymer which is prepared by polymerizing at least one alkyl acrylate monomer and at least one carboxylic polymerizable monomer selected from the group consisting of acrylic acid...     

A solution of an oxygenated polyamine, which is the reaction product of dimethylamine and epichlorohydrin, has been discovered to possess excellent stabilization properties when used as a treatment for stabilizing a clay containing formation, for example in the treatment of oil and gas producing boreholes...     

Particular methods and compositions are provided for producing an isocyanate polymer suitable as a sealing agent by using one or more typical di- or polyisocyanates with one or more alcoholic or acidic compounds and a particular catalyst namely, triethylenediamine, Groups 3 and 4 metal-organic compounds...     

A method for forming a plug in a well bore by establishing a two-phase system within the well bore. The two-phase system includes a less dense phase which bears against the upper surface of a higher density phase to provide an interface between the two phases that is positioned at a desired location...     

A method for stabilizing the soil wherein a liquid selected from the group onsisting of (1) a mixture of dimer diisocyanate and dimer diamine; and (2 ) a mixture of dimer diisocyanate and a ketimine derivative of dimer diamine is applied to the soil and allowed to polymerize to form an elastomeric resin...     

Thermally stable foamable gelled compositions suitable for post-primary oil recovery e.g., steam- or gas-foamed systems comprising water, a surfactant, a polymeric viscosifier, an aldehyde component, and at least one phenolic component such as resorcinol, catechol, and the like, as well as selected oxidized...     

Methods for the recovery of oil are provided, which include selectively plugging the water-rich portions of an oil-producing formation by injecting into the formation a swelling polymer.

An amphoteric water-in-oil self-inverting polymer emulsion is prepared which contains a copolymer of (1) a nonionic vinyl monomer and (2) an amphoteric vinyl monomer or a terpolymer of (1) a nonionic vinyl monomer, (2) an anionic vinyl monomer and (3) a cationic vinyl monomer in the aqueous phase, a...     

A method of selectively blocking high permeability flow channels in an underground hydrocarbon material bearing formation having flow channels of high permeability and having flow channels of lesser permeability. The method includes the steps of introducing a blocking material fluid comprising a blocking...     

The instant invention is directed to shear thickening fluids which comprise a water swellable clay capable of rapidly forming a paste having a strength of at least 2000 lbs/100 ft.sup.2 upon interaction with the aqueous phase employed and present in sufficient concentration to form such a paste, a nonaqueous...     

A method for selectively reducing the permeability of the higher permeability zones of a subterranean reservoir having heterogeneous permeability, such permeability reduction occurring a substantial distance away from a well in which there is injected into the reservoir an aqueous solution or solutions...     

Subterranean geological formations such as those surrounding oil well bore holes, are treated by placing in or adjacent the formation a particulate material coated with a two-step, curable, novolac-type phenolic resin. The resin is thereafter cured in situ to bond the particulate matter together. In...     

A method of plugging an elongate annulus, particularly an annulus in an oil well in which a blow-out is occurring, consists in the steps of securing hot tapping apparatus to an outer tubular member within which the annulus is situated; forming a hot tapping in the outer tubular member; injecting, through...     

A method is disclosed for selectively reducing the permeability of water producing intervals in a hydrocarbon formation without reducing oil permeability. A soluble oil followed by water is injected into the formation to lower the residual oil saturation. The well is then produced to remove water from...     

Methods are provided for selectively consolidating sand grains within a subterranean formation. First an acidic salt catalyst such as ZnCl.sub.2 is injected into the subterranean formation, wherein the acidic salt catalyst is adsorbed to the surface of the sand grains. Next a polymerizable resin composition...     

Sand or similar material coated with a polymerizable resin and catalyst is suspended in a viscous fluid carrier. Such a composition is useful for introduction into a wellbore to effect gravel packing of washed-out cavities surrounding the wellbore. The viscous fluid carrier serves to maintain a heterogeneous...     

A method for enhancing the recovery of liquid products from a wellbore having at least one laterally extending drain hole wellbore extending therefrom wherein a portion of the earth around the primary wellbore and a part of the drain hole wellbore is treated to render same essentially gas impermeable...     

An aqueous hydraulic cement slurry is disclosed which comprises water, a hydraulic cement, a surfactant and, as a fluid loss additive, epihalohydrin derivatives of polyalkylenepolyamines.

A method for reducing formation permeability comprising mixing (a) a homopolymer or copolymer of methyl acrylate or hydroxy alkyl acrylate, where the alkyl group is C.sub.2, C.sub.3 or C.sub.4, into which polymer hydrazide groups have been introduced, and (b) an aldehyde cross-linking agent, dispersing...     

A polyvinyl alcohol-aldehyde gel having a high water content and low degree of crosslinking is provided which has improved stability. The gel can be used to retard the flow of water in subterranean formation encountered in hydrocarbon production. One embodiment of the invention provides a method of forming...     

The instant invention is directed to shear thickening fluids to prevent unwanted flow in wells penetrating subterranean formations. The shear thickening fluids comprise (1) a water swellable granular clay present in sufficient quantity so that, upon interaction with an aqueous phase, a stiff paste rapidly...     

Process for treating a clayey geological formation to prevent, inhibit or reduce swelling or migrating of clay particles in a formation by treating the formation with an effective amount of a quaternized oligomer which is the reaction product of a polyamine having a primary amino group and a tertiary...     

A method for treating a subterranean formation comprised of placing in or adjacent the formation a quantity of free-flowing, heat curable particles comprised of a high strength center, a coupling agent chemically bound to the center, a heat curable resin coated over the center; and causing said free...     

A method of preventing collapse of performation tunnels extending from a well bore into a subterranean formation by filling the tunnels with self-consolidating resin coated particles and curing the resin coated particles into a permeable matrix.

A pumpable slurry of coal-filled furfuryl alcohol, furfural, and/or a low molecular weight mono- or copolymer thereof containing, preferably, a catalytic amount of a soluble acid catalyst is used to cement a casing in a geothermal well.

The disclosed invention reduces water production substantially more than hydrocarbon production in producing wells by the injection of an aqueous solution of alginates. The alginate solution or following solutions may optionally contain agents for decelerating or accelerating gelling of the alginate.

Well bores employed for production of hydrocarbons having open hole completion and zonal breakdown in the locus of the well bore are recompleted, advantageously for injection of a fluid such as CO.sub.2 in an enhanced oil recovery process. Recompletion is effected by packing off the open hole interval,...     

A process for coating geological formations and mine stoppings by applying to these substrates an aqueous, non-cementitious sealant composition comprising a water-soluble or water-dispersible polymeric binder, filler material and water, and allowing the sealant composition to dry to form an air flow...     

There is provided a new and useful bore hole plug comprising a central support member, an expandable sleeve secured about the central support, a first reactant chemical within the sleeve which is capable of reacting with a second reactant chemical or a catalyst to form a closed cell foam, and means by...     

Polymerization in-situ to effect permeability contrast correction in oil-bearing subterranean formations comprising the injection of at least one water-soluble monomer comprising N-3-oxohydrocarbon-substituted acrylamides, such as diacetone acrylamide, and optionally at least one water-soluble comonomer,...     

Subterranean formations are treated with acid, by a method comprising the steps of: (1) forming an acidizing composition by mixing an aqueous acid component with at least one water-soluble organosilicon compound; and (2) injecting the composition into the formation. Suitable organosilicon compounds include...     

This invention relates to a method of treating wells completed in subterranean formations containing unconsolidated sand particles, so as to form a permeable barrier which permits relatively free flow of liquids including petroleum therethrough while restraining the flow of sand particles into the wellbore....     

A polyvinyl alcohol-aldehyde gel having a high water content and low degree of crosslinking is provided which has improved stability. The gel can be used to retard the flow of water in subterranean formations encountered in hydrocarbon production. One embodiment of the invention provides a method of...     

There is provided a new and useful bore hole plug comprising a central support member, an expandable sleeve secured about the central support, a first reactant chemical within the sleeve which is capable of reacting with a second reactant chemical or a catalyst to form a closed cell foam, and means by...     

A method for treating a subterranean formation, or a well penetrating the formation, comprises injecting into the well an aqueous composition containing an aminopolycarboxylic acid and water-soluble organosilicon compound. By use of the method, scale is removed from well equipment and/or openings in...     

A process for sealing casing leaks comprises cleaning out the annulus between the tubing and the casing, situating a gelable mixture in the annulus at the loci of the leak in the casing, pressuring the mixture through the leak into the formation and effecting gelation of the mixture. Optionally, the...     

Aqueous gel-forming compositions are prepared by reacting for 1-10 hours at 50.degree.-95.degree. C., melamine, formaldehyde and a sulfurous acid salt with the optional addition of a gel-modifying agent and/or a gelling agent which is added to the composition immediately prior to use.

The permeability of a subterranean oil-bearing formation is controlled by the injection of an aqueous solution of a cross-linked block copolymer containing polar and non-polar segments, with the polar segments generally making up at least 50 percent, usually 60 to 99 percent, of the copolymer. The polar...     

The present invention is directed to a process for strengthening geological formations in underground mining or other operations introducing into the formation which is to be strengthened mixtures of a polyisocyanate component (a) and a polyol component (b) which react together to form polyurethanes,...     

A gel-forming composition is provided comprising a first substance selected from the group consisting of a polyvinyl alcohol, a polyvinyl alcohol copolymer, and mixtures thereof, glutaraldehyde, and water, and which does not require a separately provided acidic catalyst to crosslink and form a gel. The...     

Disclosed is a method for controlling sand flow in an producing well by forming a permeable consolidated gravel pack. Gravel is coated with a resin such as an oligomer of furfuryl alcohol containing an ester and as a catalyst an oil soluble, slightly water soluble organic acid such as anthranilic acid....     

Improved sweep efficiency is obtained in an oil recovery process wherein oil is recovered from a subterranean, viscous oil containing formation having relatively highly permeable zones and relatively low permeability zones penetrated by at least one injection well and at least one spaced apart production...     

A process for killing and suspending mixtures of hydrocarbonaceous fluid production, particulary oil, in a formation containing same which minimizes formation damage. First, a "spacer volume" of liquid containing a surfactant is directed into the formation's productive interval. Thereafter, a solidifiable...     

A method for killing and suspending hydrocarbonaceous fluid production, particularly oil and/or gas, in a formation containing same which minimizes formation damage. A solidifiable pumpable gel mixture is placed via a wellbore into the formation's productive interval and also within said wellbore. Said...     

The invention concerns a new process for plugging and/or consolidating a permeable geological formation, notably when traversed by a borehole. The process, according to this invention, comprises the following steps: (a) insertion into the formation of an overdelayed gelling compound, composed of a gelable...     

Methods are provided for selectively consolidating naturally occurring mineral grains such as sand within a subterranean formation to form a fluid permeable barrier which restrains the movement of sand particles when oil passes through the barrier. A fluid comprising a polymerizable resin such as an...     

A high strength self-consolidating particle comprised of a particulate substrate, a substantially cured inner resin coating and a fusible curable outer resin coating.

A process for killing and suspending mixtures of hydrocarbonaceous fluid production, particularly oil, in a formation containing same which minimizes formation damage. First, a "Spacer volume" of liquid containing a chemical blowing agent is directed into the formation's productive interval. Said blowing...     

A process for killing and suspending mixtures of hydrocarbonaceous fluid production, particularly oil, in a formation containing same which minimizes formation damage. First, a "spacer volume" of liquid containing a surfactant is directed into the formation's productive interval. Thereafter, a solidifiable...     

A process for killing and suspending mixtures of hydrocarbonaceous fluid production, particularly oil, in a formation containing same which minimizes formation damage. First, a "spacer volume" of liquid containing a chemical blowing agent is directed into the formation's productive interval. Said blowing...     

Methods are provided for selectively consolidating naturally occurring mineral grains such as sand within a subterranean formation to form a fluid permeable barrier which restrains the movement of sand particles when oil passes through the barrier. A fluid comprising a polymerizable monomer such as furfural...     

The present invention is directed to a process for the strengthening of geological formations in underground workings and mines by the introduction of reaction mixtures which react to form polyurethanes into the formations which are to be strengthened, the reaction mixtures being based on (a) a polyisocyanate...     

Methods and compositions for altering the water permeability of subterranean formations are provided. The compositions are comprised of water, at least one polymer capable of being gelled when contacted with a crosslinking agent, at least one crosslinking agent comprised of polyvalent metal cation, and...     

The present invention provides a method of consolidating an incompetent subterrnean formation. An acid curable resin consolidating fluid is positioned within casing in a wellbore in the vicinity of perforations through the casing. A gas generating charge positioned within the casing then is ignited to...     

Methods are provided for selectively consolidating naturally occurring mineral grains such as sand grains within a subterranean formation to form a fluid permeable barrier, which restrains the movement of said particles when oil passes through the barrier. When applied to formations in which at least...     

Hydroxyacetic acid condensation product is used as a fluid loss material in a well completion or workover process in which a fluid comprising a hydrolyzable aqueous gel is used. The hydroxyacetic acid condensation product degrades at formation conditions to provide hydroxyacetic acid which breaks the...     

A method for treating a subterranean formation, or a well penetrating the formation, comprises injecting into the well an aqueous composition containing an aminopolycarboxylic acid and a water-soluble organosilicon compound. By use of the method, scale is removed from well equipment and/or openings in...     

The permeability of a subterranean oil-bearing formation is controlled by the injection of an aqueous solution of a cross-linked block copolymer containing polar and non-polar segments, with the polar segments generally making up as least 50 percent, usually 60 to 99 percent, of the copolymer. The polar...     

Wells penetrating oil-producing and water-producing intervals may be treated in order to reduce the flow rate of water into the well by isolating the water-producing interval and introducing into it a volume of treating fluids sufficient to invade at least six inches into the water-producing interval....     

Wells penetrating oil-producing and water-producing intervals may be treated in order to reduce the flow rate of water into the well by isolating the water-producing interval and introducing into it a volume of treating fluids sufficient to invade at least six inches into the permeable formation comprising...     

Methods are provided for selectively consolidating naturally occurring mineral grains such as sand grains within a subterranean formation to form a fluid permeable barrier, which restrains the movement of sand particles when oil passes through the barrier. A sand consolidation fluid usually containing...     

An additive for well servicing fluids containing a partially hydrolyzed acrylamide for use in downhole environments having a high calcium ion content comprising an alkali metal bicarbonate, a water-soluble carboxylic acid and a copolymer of acrylamide, an acrylic acid and 2-acrylamido-2-methylpropanesulfonic...     

This invention relates to a method of treating wells completed in subterranean formations containing unconsolidated sand particles, so as to form a permeable barrier which permits relatively free flow of liquids including petroleum therethrough while restraining the flow of sand particles into the wellbore....     

An aqueous composition comprises an aminopolycarboxylic acid and a water-soluble organosilicon compound. The composition is useful for removing scale from well equipment and/or openings in a subterreanean formation, and for stabilizing fine particles within the formation to prevent their subsequent movement....     

A method of treating an underground formation is disclosed. The method comprises contacting the underground formation with a resin system comprising betwen 15 and 30% v of monomeric and/or polymeric organic polyepoxides having more than one epoxy group per molecule, between 5 and 20% v of a curing agent,...     

Disclosed are processes for treating a subterranean formation to improve the permeability distribution by reducing the permeability in high permeability zones, so fluids injected for oil recovery purposes will sweep more uniformly through the formation. The processes involve injecting a polymerizable...     

Methods are provided for consolidating unconsolidated mineral grains such as sand within a subterranean oil formation to form a fluid permeable barrier which restrains the movement of sand particles when oil passes through the barrier. A quantity of an organic solvent, preferably an ester such as butyl...     

Pathway-containing foamed gels enhance the recovery of the nonaqueous fluids from subterranean formations by selectively reducing the flow of aqueous fluids with respect to the flow of nonaqueous fluids.

A surfactant is added to a cement containing a polymer fluid loss additive, to synergistically reduce fluid loss from the cement before it hardens.

Methods of completing a well bore having a conduit disposed therein where portions of the well bore and conduit are positioned substantially horizontally in a subterranean producing formation are provided. A hardenable resin composition coated particulate solid material is placed in the annulus between...     

Drilling mud is economically disposed of in an environmentally sound manner by mixing the mud with a crosslinkable polymer and a crosslinking agent to form a composition that solidifies at a predetermined time. The composition is injected into a subterranean formation through an abandoned well and, when...     

Polymers (and especially hydroxyethylcellulose) are crosslinked using a lanthanide as a crosslinking agent. The crosslinked polymers have utility in well completion, well stimulation, enhanced oil recovery, and subterranean fluid containment operations.

Gels stable in a subterranean formation at a temperature greater than about 175.degree. F. are formed using, inter alia, a stabilizing agent (e.g., a buffer having a buffering capacity at a pH of at least about 8 and/or a chelating agent).

The present invention provides a method of temporarily plugging or sealing a subterranean formation by introducing a rapidly viscosifying liquid hydrocarbon into the formation. The method is accomplished by admixing a first component comprising an alkyl orthophosphate acid ester and an alkali metal hydroxide...     

Disclosed are methods for treating wells to form a permeable barrier around the well for consolidating unconsolidated mineral particles such as sand in a subterranean petroleum formation penetrated by a well, or for forming an impermeable barrier for fluid entry control, or for plugging the well for...     

Disclosed are methods for treating wells to form a permeable barrier around the well for consolidating unconsolidated mineral particles such as sand in a subterranean petroleum formation penetrated by a well, or for forming an impermeable barrier for fluid entry control, or for plugging the well for...     

A method for treating a formation having zones of varying permeabilities to improve the sweep efficiency of a drive fluid through the formation. At least one radial, relative horizontal bore is formed from a relative vertical wellbore and extends outward into a high-permeability zone of said formation....     

During directional drilling operation, in order to achieve the correct angle and direction when drilling through a soft formation, a plug of a non-conventional cement is set across the zone in order to achieve the desired course and target. The non-conventional cement is preferably blast furnace slag...     

Squeeze cementing is conducted using non-conventional cements such as blast furnace slag--water base drilling fluid mixtures which are not adversely affected by brine or pockets of gelled drilling fluid beneath the primary cement.