PROCESSES OF MAKING

A series of hydroxy containing ferrocene derivatives are prepared. The fecene derivatives are useful as burning rate catalysts in solid rocket propellants.

Processes for preparing vinyl nortricyclane (I) and its hydrogenated derivative, ethyl nortricyclane (II) are disclosed. The nortricyclane (II) can be used as a high energy fuel or a fuel diluent. Process involves codimerization of norbornadiene and ethylene in the presence of a homogeneous catalytic...     

The present invention relates to a pump truck for handling aqueous slurry blasting agents. The truck is designed to mix and pump the slurry without the use of augers, electrical drives, hydraulic drives, ingredient flow drive motors or other such equipment, resulting in increased safety and improved...     

This application concerns a process for generating carbon monosulfide (CS) in quantity for a carbon monoxide (CO) chemical laser using thermochemical dissociation of carbon disufide (CS.sub.2) in a high temperature (T.gtoreq. 2400 K) fuel-oxidizer flame.

A process and apparatus for preparing cap sensitive water-in-oil explosive emulsion compositions on a commercial basis is provided which includes mixing a hydrocarbon fuel component, an emulsifier, and an aqueous inorganic oxidizing salt solution under mixing conditions sufficient to obtain an emulsion...     

This invention relates to a gelled explosive and a method for its preparation. More specifically, the invention relates to a gelled explosive composition containing water, at least one member selected from the group of a polysaccharide colloid and synthetic polymer; water-soluble melamine resin and a...     

Catalytic codimerization of norbornadiene and 1,3-butadiene, using a three-component homogeneous catalytic system consisting of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl aluminum chloride, yields a codimer having the following structure: ##STR1## Upon hydrogenation,...     

A catalyst bed containing alumina pellets on which an active catalyst metal selected from iridium, nickel, niobium, and molybdenium has been deposited is employed to decompose a compound selected from deuterohydrazine, deuteroammonia, hydrazine, and ammonia to yield ammonia free deuterium and nitrogen...     

Norbornadiene and an alkyne are catalytically codimerized in the presence of a homogeneous catalytic system of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl alluminum chloride. Also, novel codimers of norbornadiene and an alkyne containing at least three carbons...     

Novel codimers (I) of norbornadiene and phenylacetylenes and their hydrogenated derivatives (II), having the following structures ##STR1## wherein R is a hydrogen, a phenyl, or a phenyl having alkyl substitutents and R.sub.1 is a phenyl or a phenyl having alkyl substituents and processes for preparing...     

The present invention relates to a pump truck for handling aqueous slurry blasting agents. The truck is designed to mix and pump the slurry without the use of augers, electrical drives, hydraulic drives, ingredient flow drive motors or other such equipment, resulting in increased safety and improved...     

A process for the manufacture of water gel explosives comprising mixing microspheres to be expanded in a concentrated solution or eutectic melt containing part of the ingredients of the finished explosive such that the microspheres can be expanded at a temperature at which there is no danger of explosion...     

A method for desensitizing explosive materials consisting of the elements carbon, hydrogen, oxygen and nitrogen, comprises contacting the explosive material with a reductant containing no elements besides those contained in the explosive material for a period of time sufficient to desensitize said explosive,...     

A process is described for the comminution of a solid material in the presence of a saturated solution of the solid in a liquid in which the solid has a solubility greater than 1%, and also in the presence of an additive dissolved in the saturated solution which can at least partially inhibit regrowth...     

A high density fuel composition having low temperature operational capability for propelling turbo-jet, limited volume missile systems consisting essentially of at least 95 weight percent exo-tetrahydrodicyclopentadiene (JP-10) and a correspondingly minor amount of a C.sub.3 -C.sub.7 saturated hydrocarbon.

A slurry composition based essentially on ammonium nitrate, prepared by a process which comprises comminuting solid substance containing ammonium nitrate by grinding in the presence of a saturated solution of solid in a liquid in which the solid has a solubility greater than 1% by weight, the mixture...     

An improved method for producing known primer constituents lead styphnate and barium nitrate, in situ, plus water. The process is carried out by reacting effective amounts of trinitroresorcinol (TNR), with barium hydroxide, or barium carbonate, and lead nitrate in water.

It has been discovered that when co-nitrating a mixture of trimethylolethane and diethylene glycol, a storage stable spent acid can be obtained if during the co-nitration an excess of from about 60 to about 100% by weight of nitric acid over that stoichiometrically required is employed.

A direct process of making ethylenediamine dinitrate through the reaction of ethylenediamine and ammonium nitrate.

The present invention provides a method of tagging a substance to allow subsequent identification thereof comprising incorporating in the substance a polypeptide. Typically, the polypeptide is a synthetic polypeptide having a specific sequence of amino acids to constitute a particular molecular code...     

A process is disclosed by which thermoplastic elastomers may be utilized to repare melt-formable composite rocket propellants. The thermoplastic elastomer is dissolved in a volatile organic solvent, the other propellant ingredients are mixed in, and the volatile organic solvent is evaporated. The dried...     

This invention relates to propellants and in particular to a method for safely forming a binary propellant. More specifically, this invention relates to a method for safely forming a Binary Propellant useful as a propellant replacement for Black Powder.

A powder explosive composition comprising particulate inorganic oxidizing salt, finely divided metal sensitizer and, optionally additional fuel consisting of discrete granules containing oxidizing salt and sensitizing metal coated with a tough, cohesive, resilient gelled solution of the oxidizing salt,...     

A high density specialty fuel for propelling limited volume ramjet and turbojet missile systems comprising a blend of at least 70 weight percent of exotetrahydrodicyclopentadiene and a correspondingly minor amount of a combination of a mixture of C.sub.5 -C.sub.7 alkanes and/or cycloalkanes and hydrogenated...     

This application relates to the art of pyrotechnics and specifically concerns an improvement in the process for preparing granulated pyrotechnic compositions.

A method of producing a priming composition comprising reacting components to produce a primary explosive and a by-product which remains in the composition.

Sensitive explosive materials such as RDX or HMX may be desensitized by stirring them up with micronised wax in a liquid medium, usually water. The wax is in the form of particles having a mean size of less than 20 microns, preferably less than 6 microns, and particularly preferred is a wax having a...     

A process for desensitizing sensitive explosives materials such as RDX or HMX involves stirring a paste of the explosives material in a liquid medium, usually water, with a wax which will soften below the safe decomposition temperature of the explosives material, heating the mixture to drive off the...     

The present invention relates to an improved explosive TNT based composit consisting of TNT, HDX, RDX, aluminum and a small amount of an elastomeric linear polymer having polar groups dissolved or dispersed throughout, said composition having improved properties. Such improved properties include: reduced...     

A method and apparatus is provided for the efficient and safe manufacture of batch quantities of non-cap-sensitive emulsion explosives. The method employs none of the high shear mixing or homogenizing techniques of the prior art and hence hazards from heat and mechanical breakdown (impact) are eliminated....     

A gunpowder substitute which is capable of also being molded into a consumable cartridge or cartridge case comprising between 50% to 75% by weight of an inorganic nitrate and between 25% to 50% by weight of an organic acid including ascorbic acid, erythorbic acid and mixtures thereof.

The present invention relates to an emulsion explosive of the water-in-oil type having resistance against dissolution in water, and application of said emulsion in explosive mixtures. The emulsion explosive is non cap-sensitive and can be cartridged alone or in mixture with ANFO. It can also be used...     

A method for making a water-in-oil emulsion type explosive composition is disclosed. The method comprises combining a liquid carbonaceous fuel and an aqueous solution of at least one inorganic oxidizing salt, with agitation, in the presence of ingredients A and B and incorporating dispersed gas bubbles...     

An incendiary mixture which is constituted of metals with at least one oxygen-supplying metal oxide and an organic binder, and/or a nitrate, chlorate, perchlorate or peroxide selected from the group of elements consisting of sodium, potassium, lithium, barium, strontium, as well as compounds of ammonium.

A pelletized propellant particularly suitable for crash restraint device inflation apparatus comprising an alkali metal azide, an oxidizing agent, and a metal oxide formed by dehydrating a hydrated oxide formed in situ, the burn time and sensitivity of the composition being adjusted to produce the necessary...     

A process of making mixed, stable explosives from emulsions, the resulting omposite having a greater degree of energy available for release.

The invention relates to a cast explosive composition having a high density, energy and critical diameter and comprising inorganic oxidizer salt consisting primarily of ammonium nitrate, a water-immiscible organic liquid fuel, less than about 5% water, and an emulsifier which allows formation of a water-in-oil...     

An azidonitrate energetic composition i.e. cellulose azidonitrate and a pess of making the same from nitrocellulose and sodium or lithium azide.

Explosives that are sensitized blends of inorganic nitrate, e.g., AN, particles, such as AN or ANFO prills, and an aqueous slurry comprising a thickened aqueous solution of an inorganic oxidizing salt, preferably AN, are rendered storage-stable by keeping the slurry's water content low enough, and its...     

A gas bubble sensitized water-in-oil emulsion explosive composition comprising a discontinuous aqueous phase comprising at least one oxygen-releasing salt, a continuous water-immiscible organic phase, a discontinuous gaseous phase, a water-in-oil emulsifying agent and at least one agent capable of facilitating...     

A process for producing double base propellant powders deterred with Vinsol by diluting the Vinsol with isopropyl alcohol or similar solvent and then adding the solvent Vinsol solution to the propellant powder in a sweetie barrel in an intermittent manner proceeded by addition of graphite.

Method of stabilizing an emulsion explosive comprising an oxidant, a fuel, and an emulsifier the molecules of which have at least one double-binding. The oxidant is emulsified in the fuel in the presence of the emulsifier, and a polymerizing reaction is effected after the emulsification to bind the molecules...     

Method and apparatus for making aqueous slurry explosives are disclosed. The components of the aqueous slurry explosive are mixed in a variable speed rotary mixer where the speed of the mixer is determined by the sequence of addition of the explosive components. The explosive components generally comprise...     

In emulsion blend explosives, the replacement of coarse salt particles, e.g., prills, by fines, i.e., particles which pass a No. 50 U.S. sieve, increases the water resistance of the explosive without deleteriously affecting its shelf life provided that the explosive, prior to such replacement, is storage-stable...     

High density water gel explosives having relatively large amounts of low density sensitizers are prepared by evenly dispersing a densifying material therethrough. Separation of the densifying material during the mixing and packaging of the water gel explosive is prevented by adding from about 0.1 to...     

The invention provides a method of priming a blank or bulleted rimfire cartridge comprising the steps of (a) dosing into the rimfire case a quantity of a substantially dry, powdery, relatively insensitive premix comprising, in predetermined proportions, at least two materials that will, in the presence...     

This invention relates to the preparation of gas bubble-sensitized explosive compositions which are liquid during their manufacture. It is possible to achieve particularly fine bubble sizes and therefore enhanced explosive power by incorporating in the liquid composition a gas bubble-generating agent...     

The present invention relates to a cast explosive composition and other energetic compositions such as propellants. (As used herein, the term "explosive" also shall include other energetic compositions such as propellants.) More particularly, the invention relates to a cast explosive composition which...     

Method and apparatus for making aqueous slurry explosives are disclosed. The components of the aqueous slurry explosive are mixed in a variable speed rotary mixer where the speed of the mixer is determined by the sequence of addition of the explosive components. The explosive components generally comprise...     

A packaged booster charge is provided which is sensitive to initiation by blasting cap yet which contains no self-explosive ingredient. The composition of the booster comprises a low melting point nitrate salt or salt mixture having dissolved or finely dispersed therein an acetylenic substance and void...     

A water resistant explosive composition is disclosed for use in wet blasting holes. The composition comprises ammonium nitrate prills coated with a glycol and oil emulsion to render the prills waterproof. The coated prills are mixed with quick hydrating and self-complexing guar gums. The compositions...     

The shock sensitivity of explosives based on ammonium nitrate can be decreased by adding thereto a desensitizing amount of a polyethyleneimine or a polyethyleneimine polynitrate.

An emulsion explosive comprising substantially an immiscible discontinuous oxidizer-phase dispersed throughout a continuous fuel phase with a modifier comprising hydrophilic and lipophilic moieties wherein the hydrophilic moiety comprises a carboxylic acid group or a group capable of hydrolyzing to a...     

In emulsion blend explosives, the replacement of coarse salt particles, e.g., prills, by fines, i.e., particles which pass a No. 50 U.S. sieve, increases the water resistance of the explosive without deleteriously affecting its shelf life provided that the explosive, prior to such replacement, is storage-stable...     

Certain classes of organic acids, and salts of those acids and in particular ascorbic acid and erythorbic acid and the salts thereof, and mixtures thereof, which have certain antioxidant and food preservative properties, have been found to be capable of being reacted together with sources of nitrate,...     

A less sensitive explosive, 3-nitro-1,2,4-triazol-5-one. The compound 3-nitro-1,2,4-triazol-5-one (NTO) has a crystal density of 1.93 g/cm.sup.3 and calculated detonation velocity and pressure equivalent to those of RDX. It can be prepared in high yield from inexpensive starting materials in a safe synthesis....     

The invention relates to a waterproof, free-running blasting agent and method of manufacturing the same and, more particularly, to a blasting agent in the form of microcapsules (small spherical-shaped particles comprising fluid or hardened droplets surrounded by a hardened shell material). The microcapsules...     

Solid propellant is first placed in a closed container with a solution of ter and detergent. A water slurry is then created by injecting compressed air in superheated steam into the solution to place the propellant and solution under several atmospheres of pressure and at the same time to raise the temperature...     

A water-in-oil emulsion explosive composition comprising: a discontinuous aqueous oxidizer-phase comprising dissolved therein an oxygen releasing salt component comprising ammonium nitrate; a continuous organic-phase comprising an organic fuel; and an emulsifying agent and characterized in that the oxygen-releasing...     

Low alloy steel tubes are decarburized, heavily diffusion chromized and heavily diffusion aluminized to protect them against sulfidation. For the diffusion they can be supported upright with one end on layer of diffusion-coating pack on floor of a retort. Surface portions that are to be welded are covered...     

An emulsion explosive composition comprising a discontinuous phase containing an oxygen-supplying component and an organic medium forming a continuous phase wherein the oxygen-supplying component and organic medium are capable of forming an emulsion which, in the absence of a supplementary adjuvant,...     

A method for the pre-emulsification of fuel oil or other carbonaceous compound and water in the presence of one or more emulsifying compositions or emulsifier constituents, prior to the addition to and emulsification of an aqueous solution of the ammonium nitrate or other oxidizer salt. In contrast to...     

A water-in-oil emulsion is disclosed which comprises: (A) a continuous oil phase; (B) a discontinuous aqueous phase; (C) a minor emulsifying amount of at least one salt derived from (C) (I) at least one hydrocarbyl-substituted carboxylic acid or anhydride, or ester or amide derivative of said acid or...     

This invention relates to a method of producing a composition comprising solid particulate ammonium nitrate having improved explosive properties. Explosive compositions comprising particulate ammonium nitrate such as ANFO, which is a mixture of particulate ammonium nitrate and about 6% w/w of a fuel...     

A method for preparing 2,6-bis(picrylamino)-3,5-dinitropyridine (PYX) which includes the steps of first dissolving crystalline PYX in a primary solvent in which the solvent used is selected from the group consisting of pyridine, dimethylformamide, methylsulfoxide or mixtures thereof. The primary solvent...     

Water-containing explosives, such as emulsions, slurries and water gels, are sensitized in their salt phase with sensitizing energy release agents based on nitroalkanes and nitroalkane blends and optionally including arene coupling agents.

The present invention provides a means by which chemically or thermally gassed emulsion explosives can be packaged in symmetrical cartridges, such as cylindrical paper packages having crimped ends. After formation, the gassed emulsion explosive is formed into a continuous strip of generally constant...     

Apparatus for producing a multi-phase emulsion explosive from a liquid organic fuel medium and an immiscible liquid oxidizer comprises a mixing chamber, flow constrictor means for introducing the liquid oxidizer as an emergent turbulent jet to said chamber and causing formation of droplets of said oxidizer...     

Automotive airbag gas generant formulation providing an alternative to commercially used formulations containing sodium azide. The composition contains from about 25% to about 75% by weight of 5-nitro-1,2,4-trizal-3-one (usually known as nitrotriazolone). The other principal ingredient of the composition...     

A process for preparing a gas bubble sensitized explosive composition. The present process comprises preparing an explosive composition comprising a water-in-oil emulsion and mechanically entraining gas bubbles into the explosive composition. Low viscosity emulsion explosives are able to be sensitized...     

A binary munition system comprising at least two non-explosive ingredients hat combine in flight to form a relatively safe explosive. The combination of said non-explosive ingredients for the purpose of forming safe explosives is novel. The binary munition stores the non-explosive ingredients in separate...     

The invention provides an apparatus for the manufacture of a coarse emulsion blasting agent and a method for the conversion of same into a sensitive blasting explosive. The apparatus comprises a low shear mechanical mixer in which a coarse emulsion can be continuously prepared. The coarse emulsion is...     

A method for preparing 2,6-bis(picrylamino)-3,5-dinitropyridine (PYX) which includes the steps of first dissolving crystalline PYX in a primary solvent in which the solvent used is selected from the group consisting of pyridine, dimethylformamide, methylsulfoxide or mixtures thereof. The primary solvent...     

A high impulse, non-detonable solid propellant grain is prepared from a cd detonable proepllant composition having a small critical diameter of less than one inch and an uncured detonable propellant composition having a large critical diameter of several inches. The method of preparation comprises grinding...     

An extrudable plastic bonded explosive molding powder is provided and conns about 20 percent by weight ethylenevinyl acetate copolymer and 80 percent by weight PETN.

The present invention relates to an improved explosive composition. More particularly, the invention relates to a water-in-oil emulsion explosive that is sensitized by chemically formed gas bubbles. The water-in-oil emulsion explosives of this invention contain a water-immiscible organic fuel as the...     

Primer composition comprising diazodinitrophenol or potassium dinitrobenzofuroxane, tetracene, nitrate ester fuel and strontium nitrate. It is prepared by hydrating anhydrous strontium nitrate by dissolving in warm water and thereafter cooling solution to obtain crystals of the tetrahydrate. These crystals...     

A permitted water-bearing explosive composition of the watergel or emulsion type contains a suitable amount, e.g. 0.5% by weight of the composition, of a non-passivated paint flake aluminum having a surface area of 5000 cm.sup.2 /g or greater and a suitable amount of one or more alkali or alkaline earth...     

The invention provides a pyrotechnic composite and process for preparing the same, wherein the pyrotechnic composite comprises a mixture of an alkaline earth metal sulfate, particulate boron and at least one additional particulate metal which is capable of exothermically reacting with boron. The exothermic...     

The present invention provides a method for producing a water-in-oil emulsion and the emulsion explosives therefrom containing nitrostarch by nitrating starch with an excess of a nitrating agent, treating the reaction mixture thereof with anhydrous ammonia to form a solution of water, dissolved ammonium...     

A composition comprising phosphorus and a minor amount of at least one radical inhibitor selected from 4-(p-n-trophenyl-azo)-1-naphthol and mono and fused bi- and tri-cyclic compounds bearing at least a first and a second substituent, the first substituent being selected from hydroxy, mercapto, oxo,...     

A castable, thermoplastic composite rocket propellant comprising about 3 to 10 wt % of a thermoplastic elastomer, about 3 to 20 wt % of a plasticizer, balance energetic particulates is provided. Also provided is a process for producing a thermoplastic composite rocket propellant which comprises melt...     

A method for producing an emulsion explosive comprises introducing a liquid organic fuel phase and an immiscible liquid oxidizer phase into apparatus having a mixer chamber, flow constrictor means for introducing the liquid oxidizer phase as an emergent turbulent jet into the chamber to cause its fragmentation...     

A chemically sensitized dry explosive is provided, which can be used as a blasting agent, per se, or can be used in the production of a wide variety of explosive compositions. The compositions are typically manufactured from an unstable emulsion explosive and have a chemical sensitizer in either the...     

A process for the production of a chemically gassed emulsion explosive wherein a chemical gassing agent is added to the emulsion as an essentially dry particulate powder. The process allows for the production of stable emulsion explosives which have more controllable emulsion explosive characteristics.

Water-containing explosives, such as emulsions, slurries and water gels, are sensitized in their emulsion (concentrate) phases with sensitizing energy release agents based on nitroalkanes and nitroalkane blends including arene coupling agents. The sensitizing energy release agents are miscible with the...     

A castable smoke-producing pyrotechnic composition comprising a hydroxy-terminated azido polymer binder with a polyisocyanate curative, an energetic plasticizer, and a dye in an amount sufficient to generate colored smoke.

Solid propellant test strands are inhibited, i.e., prevented from burning in an uncontrolled fashion, by coating the strands with a liquid composition containing a partially cured phenolformaldehyde in a volatile solvent, then volatizing the solvent.

A multicomponent explosive composition and its use as a blasting agent in ditching operations and the like. The explosive comprises a fuel component and an oxidizer compnent, both of which are retained in the liquid state over wide temperature ranges and are stable over long storage intervals. The fuel...     

A method and composition for enhancing the visual effect of a combustion explosion without substantially increasing the explosive force is the subject matter of this invention. A solid explosive compound is combined with a ground combustible particulate material that is characterized by a wide distribution...     

A gas generating grain has a water-based particulate booster coating thereon. The coating comprises an alkali metal azide, a water-soluble inorganic oxidizer in approximately a stoichiometric proportion of oxidizer to azide, and a nucleating amount of a small particle size metal oxide, preferably selected...     

An explosive composition having a combination of a principal explosive, which is relatively insensitive to initiation of detonation, two mesh fractions of a sensitizing explosive which is relatively sensitive to initiation of detonation, a critical diameter additive which lowers the critical diameter...     

The particle size of energetic explosive materials is reduced by slurrying the particulate explosive materials in an inert liquid such as water or an aqueous solution, and subjecting the slurry to intense acoustic cavitation from an ultrasonic generator for a short time. The particulate explosive materials...     

The present invention relates to a method for producing, by means of working, mixing and homogenizing, castable explosive substances of high viscosity containing crystalline and/or particulate explosives and, if appropriate, other action-enhancing additives and such small quantities of binder and other...     

A solid propellant to inhibitor bonding system for use in replaceable prolant grain assemblies is used with an inhibitor sleeve that has one end attached to an end closure having interior insulation, made of the same rubber insulation material as the inhibitor, and forming a cylindrical cavity for receiving...     

The invention relates to a method for stabilizing a detonable mixture of emulsion and AN or ANFO prills and to the resulting compositions. A surfactant is dissolved in a liquid organic fuel prior to adding the fuel to AN prills for forming ANFO prills, or if AN prills are used without added liquid organic...     

This invention relates to an explosive. It relates in particular to the manufacture of an emulsion explosive comprising a discontinuous phase which forms an oxidizing salt-containing component and a continuous phase which is immiscible with the discontinuous phase and which forms a fuel component.

A process for making a body of gas generating material comprising the steps of preparing a slurry of the ingredients of said gas generating material; extruding said slurry into a plurality of extrudate; forming the extrudate into spherical granules; and pressing a plurality of granules to form a unitary...     

Waste solid energetic compositions such as waste solid rocket propellant are desensitized for purposes of disposal and burning by being combined with a diluent and a filler which lower the sensitivity, energy output and flame temperature of the compositions and improve their ability to burn in a controlled...     

The present invention relates to modified propellant compositions of either single or multiple based type which are obtained by resolvating a conventional, previously solvated nitrocellulose-based granular propellant with a solvent such as methyl ethyl ketone followed by the addition of glycerine to...